MSDS sheet

Corporate Office: 850709 Hwy 17 Yulee, FL 32097 Phone 904-225-1047 Fax 904-225-1048

MATERIAL SAFETY DATA SHEET

Trade name: MaxAmine MaxLinerAR-A

CHEMICAL FAMILY: ISOCYANATE

TRANSPORTATION EMERGENCY ASSISTANCE / CALL CHEMTREC / 1 (800) 424 - 9300

NFPA HAZARD RATING

DEGREE OF HAZARD: 4=EXTREME 3=HIGH 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT

SECTION II (HAZARDOUS SUBSTANCES)

* THIS CHEMICAL IS SUBJECT TO SARA TITLE III, SECTION 313 REPORTING

SECTION III (PHYSICAL DATA)

BOILING POINT: N/A WEIGHT PER GALLON: 9.41 +0.3 lbs.

% VOLATILE BY VOLUME: No data EVAPORATION RATE (ether=1): No data

VAPOR DENSITY (air=1): 8.5 approx. VAPOR PRESSURE: <0.0003 mmHG @ (20°C/68°F)

SECTION IV (FIRE & EXPLOSION HAZARD DATA)

FLASH POINT: >150°F

EXTINGUISHING MEDIA: Foam, CO2, dry chemical, halogenated agents.

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters must wear self-contained breathing apparatus and full protective clothing to prevent contact with toxic and/or irritating fumes. Do not spray pool fires directly; a stream of water directed into hot, burning liquid can cause frothing.


UNUSUAL FIRE & EXPLOSION HAZARD: Contamination of isocyanate component with water will generate carbon dioxide gas with possible pressure build up in confined areas. Incomplete combustion may produce carbon monoxide. It is unlikely that this product will explode due to mechanical impact. Containers may burst under intense heat.

SECTION V (HEALTH HAZARD DATA)

EFFECTS OF OVEREXPOSURE: Inhalation of high concentrations may cause isocyanate sensitization. Skin contact can cause severe irritation, possible burns, defatting, and dermatitis. Eye contact causes sever irritation, redness, tearing, and blurred vision.
EMERGENCY & FIRST AID: If overcome by vapors, remove to fresh air and if breathing has stopped, give artificial respiration. Eye contact: Flush immediately with water and call a physician as soon as possible. Skin contact: Wash with soap and water and remove contaminated clothing. Ingestion: See a physician as soon as possible.

PRIMARY ROUTE OF ENTRY: Dermal or inhalation most likely.

MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: Repeated exposure can cause allergic reaction with development of occupational asthma. Long-term exposure to low vapor concentrations may cause chronically progressive pulmonary disease. Repeated skin contact can result in sensitization.



SECTION VI (REACTIVITY DATA)

STABILITY: Stable

CONDITIONS TO AVOID: Heat, sparks, open flame and water contamination.

INCOMPATIBILITY: Water, alcohols, liquid chlorine, concentrated oxygen, NaOH, amines, alkaline materials and organometallic compounds.

HAZARDOUS DECOMPOSITION PRODUCTS: Burning may produce nitrogen oxides, hydrogen cyanide, carbon monoxide and/or carbon dioxide.

HAZARDOUS POLYMERIZATION: May occur at elevated temperatures in the presence of alkalies, tertiary amines and metal compounds.

SECTION VII (SPILL OR LEAK PROCEDURES)

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. In enclosed areas, cleanup personnel should wear self-contained breathing apparatus. Cover spills with sawdust, vermiculite, or other absorbent material. Add an equal volume of a 6% ammonia solution in water and allow to react for 10 minutes. Collect into open containers and add more solution. Cover loosely to vent carbon dioxide gas generated.
WASTE DISPOSAL METHOD: Dispose in accordance with local, state, and federal regulations.

SECTION VIII (SPECIAL PROTECTION INFORMATION)

RESPIRATION PROTECTION: Use organic vapor canister for low concentrations. Use self-contained breathing apparatus in enclosed areas involving higher vapor concentrations.

VENTILATION (Local/Mechanical Exhaust): Explosion proof mechanical equipment capable of keeping vapor concentration below the TLV.

PROTECTIVE GLOVES: Chemical resistant neoprene, nitrile-butadiene or butyl rubber gloves.

EYE PROTECTION: Safety goggles or face shield.

OTHER PROTECTIVE EQUIPMENT: Eye bath & safety shower should be available.

SECTION IX (SPECIAL PRECAUTIONS & TOXICOLOGICAL PROPERTIES)

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING & STORING: Keep containers closed and store in a cool dry place with adequate explosion proof ventilation. Keep away from heat, sparks, open flame and moisture. Open container should be blanketed with dry nitrogen before resealing if there is no moisture contamination. If water contamination is suspected, do not reseal. Ground equipment to prevent accumulation of static charge.

TOXICOLOGICAL PROPERTIES: The International Isocyanate Institute is currently sponsoring a lifetime study on polymeric MDI in rats for carcinogenicity. Monomeric MDI is positive for mutagenicity in the Ames assay. Oral LD50 (rats) is greater than 15800 mg/Kg. Dermal LD50 (rabbits) is greater than 7900 mg/Kg. Inhalation LC50 (rats - 2hr) is greater than 400 mg/M3 on dust of monomeric MDI. Harmful or fatal if swallowed. Vapor harmful. May cause skin or eye irritation.

CHEMICAL FAMILY: POLYAMINE

TRANSPORTATION EMERGENCY ASSISTANCE / CALL CHEMTREC / 1 (800) 424 - 9300

NFPA HAZARD RATING

DEGREE OF HAZARD: 4=EXTREME 3=HIGH 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT

SECTION II (HAZARDOUS SUBSTANCES)

SECTION III (PHYSICAL DATA)

BOILING POINT: > 400°F
WEIGHT PER GALLON: 11.04 + 0.3 lbs.

% VOLATILE BY VOLUME: Non-volatile
EVAPORATION RATE (ether=1): No data

VAPOR DENSITY (air=1): N/A
VAPOR PRESSURE: 1 mmHG @ 100°C



SECTION IV (FIRE & EXPLOSION HAZARD DATA)

FLASH POINT: >300°F (PMCC)

EXTINGUISHING MEDIA: Foam, CO2, dry chemical, water fog.

SPECIAL FIRE FIGHTING PROCEDURES: Firefighters must wear self-contained breathing apparatus and full protective clothing to prevent contact with toxic and/or irritating fumes. Water or foam may cause frothing. Use water to cool fire exposed containers.

UNUSUAL FIRE & EXPLOSION HAZARD: Toxic levels of ammonia, combustion products of nitrogen, carbon monoxide, carbon dioxide, irritating aldehydes and ketones may be formed on burning in a limited air supply. This product is non-flammable and will not explode due to mechanical impact.

SECTION V (HEALTH HAZARD DATA)

EFFECTS OF OVEREXPOSURE: Skin contact can be moderately irritating; can cause redness and drying of skin. Eye contact causes irritation, experienced as pain with excess blinking and tear production, and seen as extreme redness and swelling of the eye and chemical burns of the eye. Severe eye damage may cause blindness. Ingestion may cause abdominal discomfort, nausea, and diarrhea.

EMERGENCY & FIRST AID: Eye contact: Flush with water for at least 15 minutes and call a physician as soon as possible. Skin contact: Wash with soap and water and remove contaminated clothing. Ingestion: DO NOT INDUCE VOMITING. Give large quantities of water, and see a physician immediately.
PRIMARY ROUTE OF ENTRY: Skin, eyes, ingestion, inhalation.

MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: There is no evidence that this product aggravates an existing medical condition.

SECTION VI (REACTIVITY DATA)

STABILITY: Stable

CONDITIONS TO AVOID: Temperature extremes.

INCOMPATIBILITY: This material reacts violently with acids and isocyanates.

HAZARDOUS DECOMPOSITION PRODUCTS: Toxic levels of ammonia, combustion products of nitrogen, carbon monoxide, carbon dioxide, irritating aldehydes, and ketones may be formed in a limited air supply.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION VII (SPILL OR LEAK PROCEDURES)

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Recover free liquid. Ventilate area. Avoid personal contact. Wear appropriate personal protective equipment, including appropriate respiratory protection. Cover remaining spill with sawdust, vermiculite, or other absorbent material to minimize spreading before collecting for disposal. Place in an open container.

WASTE DISPOSAL METHOD: Dispose in accordance with local, state, and federal regulations.

SECTION VIII (SPECIAL PROTECTION INFORMATION)

RESPIRATION PROTECTION: None required unless material is being heated, then use appropriate
NIOSH or MSHA approved air purifying or air supplied respirator.

VENTILATION (Local Exhaust): Good general ventilation.

PROTECTIVE GLOVES: Latex or neoprene rubber gloves.

EYE PROTECTION: Safety goggles with splashguards.

OTHER PROTECTIVE EQUIPMENT: Eye bath & safety shower should be available.

SECTION IX (SPECIAL PRECAUTIONS & TOXICOLOGICAL PROPERTIES)

SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING & STORING: Keep containers closed and store in temperatures of 60-90°F.

TOXICOLOGICAL PROPERTIES: Available data shows that none of the ingredients are carcinogenic, teratogenic, or mutagenic. However, swallowing this material may be harmful or fatal.

KEEP OUT OF REACH OF CHILDREN!!

CORPORATE OFFICE: 11504 Boote Blvd Jacksonville Florida 32218 Phone 904-751-0652 Fax 904-751-0653

THIS INFORMATION AND TECHNICAL ADVICE PROVIDED HEREIN ARE BELIEVED TO BE RELIABLE AND ACCURATE TO THE BEST KNOWLEDGE OF SprayMax Industrial Coatings., AS BASED ON TESTS AND SHOULD SERVE ONLY AS A RECOMMENDATION. AS THE MANUFACTURER, SprayMax Industrial Coatings MAKES NO REPRESENTATIONS OR WARRANTIES OF ANY KIND, EXPRESSED, IMPLIED OR STATUTORY, INCLUDING BUT NOT LIMITED TO ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR USE OR A PARTICULAR PURPOSE FOR THE PRODUCT. SprayMax Industrial Coatings MAKES NO REPRESENTATIONS OR WARRANTIES AS TO THE RESULTS OF THE USE OF THE PRODUCT AND ASSUMES NO OBLIGATION OR LIABILITY IN CONNECTION THEREWITH. SprayMax Industrial Coatings . IS NOT LIABLE FOR ANY INCIDENTAL OR CONSEQUENTIAL DAMAGES OF ANY SORT FROM USE OF THIS PRODUCT. THE INFORMATION PROVIDED HEREIN IS SUBJECT TO CHANGE AT ANY TIME WITHOUT NOTICE. INFORMATION CHANGES MAY INCLUDE, BUT ARE NOT LIMITED TO, COMMERCIAL AND TECHNICAL CHANGES, CHANGES IN PRICING, PHYSICAL CHARACTERISTICS AND PACKAGING.